RAMON BOSQUE PUEYO

RAMON BOSQUE PUEYO

Associate professor

Scopus Author ID: 6701730645
Researcher ID: D-1635-2012
Knowledge area: Química Inorgànica

Research group: Química Organometàl·lica

Contact Information
Department of Inorganic and Organic Chemistry
C/Martí i Franqués, 1-11
934039134
ramon.bosque(a)ub.edu

Academic training

Química . Universitat de Barcelona . 06/1989 . (Diploma / Degree / Activities)
Grado de Licenciatura . Universitat de Barcelona . 02/1991 . (Diploma / Degree / Activities)
Química . Universitat de Barcelona . 12/1994 . (Ph.D.)

Journal Publications

Albert, J.; Bosque, R.; Cadena, M.; D'-Andrea, L.; Granell, J.; González, A.; Quirante, J.; Calvis, C.; Messeguer, R.; Badía, J.; Baldomà, L.; Calvet, T.; Font-Bardia (2014). A New Family of Doubly Cyclopalladated Diimines. A Remarkable Effect of the Linker between the Metalated Units on Their Cytotoxicity. Organometallics, 33(11), pp. 2862 - 2873 . Institutional Repository . ISSN: 0276-7333
Albert, J.; Bosque, R.; Crespo, M.; García, G., Granell, J.; Concepción López, C.; Lovelle, M. V.; Romana Qadir, R.; González, A.; Jayaraman, A.; Mila, E.; Cortés, R.; Quirante, J.; Calvis, C.; Messeguer, R.; Badía, J.; Baldomà, L.; Cascante, M. (2014). Cyclopalladated primary amines: a preliminary study of antiproliferative activity through apoptosis induction. European Journal of Medicinal Chemistry, 84, pp. 530 - 536 . https://doi.org/10.1016/j.ejmech.2014.07.046 . ISSN: 0223-5234
Albert, J.; Bosque, R.; Crespo, M.; Granell, J.; López, C.; Martín, R.; González, A.; Jayaraman, A.; Quirante, J.; Calvis, C.; Badía, J.; Baldomà, L.; Font-Bardia, M.; Cascante, M.; Messeguer, R. (2015). Neutral and ionic platinum compounds containing a cyclometalated chiral primary amine: Synthesis, antitumor activity, DNA interaction and topoisomerase I - cathepsin B inhibition. Dalton Transactions, 44(30), pp. 13602 - 13614 . Institutional Repository . ISSN: 1477-9226
Bartocci, S.; Sabate, F.; Bosque, R.; Keymeulen, F.; Bartik, K.; Rodriguez, L.; Dalla Cort, A. (2016). Colorimetric and fluorescence 'turn-on' recognition of fluoride by a maleonitrile-based uranyl salen-complex. Dyes and Pigments, 135, pp. 94 - 101 . Institutional Repository . ISSN: 0143-7208
Clemente, M.; Halil Polat, I.; Albert, J.; Bosque, R; Crespo, M.; Granell, J.; López, C.; Martínez, M.; Quirante, J.; Messeguer, R.; Calvis, C.; Badía, J.; Baldoma, L.; Font-Bardia, M.; Cascante, M. (2018). Platinacycles Containing a Primary Amine Platinum(II) Compounds for Treating Cisplatin-Resistant Cancers by Oxidant Therapy. Organometallics, 37(20), pp. 3502 - 3514 . Institutional Repository . ISSN: 0276-7333
Oyarzo, J.; Acuña, A.; Klahn, H.; Arancibia, R.; Silva, C.P.; Bosque, R.; López, C.; Font-Bardia, M.; Calvis, C.; Messeguer, R. (2018). Isomeric and hybrid ferrocenyl/cyrhetrenylaldimines: a new family of multifunctional compounds. Dalton Transactions, 47, pp. 1635 - 1649 . Institutional Repository . ISSN: 1477-9226
Reig, Marta; Bosque, Ramon; Font-Bardia, Merce; Calvis, Carme; Messeguer, Ramon; Baldoma, Laura; Badia, Josefa; Velasco, Dolores; Lopez, Concepcion (2018). A study of the properties, reactivity and anticancer activity of novel N- methylated-3-thiazolyl or 3-thienyl carbazoles and their Pd(II) and Pt(II) complexes. Journal of Inorganic Biochemistry, 184, pp. 134 - 145 . Institutional Repository . ISSN: 0162-0134
Juan Oyarzo; Ramón Bosque; Patricia Toro; Carlos P. Silva; Rodrigo Arancibia; Mercè Font-Bardía; Vania Artigas; Carme Calvis; Ramon Messeguer; A. Hugo Klahn; Concepción López (2019). A novel type of organometallic 2-R-2,4-dihydro- 1H-3,1-benzoxazine with R = [M(η5-C5H4)(CO)3] (M = Re or Mn) units. Experimental and computational studies of the effect of substituent R on ring-chain tautomerism. Dalton Transactions, 48(3), pp. 1023 - 1039 . Institutional Repository . ISSN: 1477-9226
Bosque, R.; Crespo,M.; Escolà, A.; Font-Bardia, M. (2018). Mono and dinuclear bis(ortho-tolyl)platinum(II) compounds containing diethyl sulfide ligands: Synthesis, DFT studies and use as precursors in cycloplatination reactions. Journal of Organometallic Chemistry, 854, pp. 122 - 130 . Institutional Repository . ISSN: 0022-328X
Bartocci, Silvia; Sabate, Ferran; Mihan, Francesco Yafteh; Bosque, Ramon; Rodriguez, Laura; Cort, Antonella Dalla (2017). Novel uranyl(VI) complexes incorporating ethynyl groups as potential halide chemosensors: an experimental and computational approach. Supramolecular Chemistry, 29(11), pp. 922 - 927 . https://doi.org/10.1080/10610278.2017.1361036 . ISSN: 1061-0278
Albert, J.; Bosque, R.; D'Andrea, L.; Durán, J.A.; Granell, J.; Font-Bardia, M.; Calvet, T. (2016). Synthesis and crystal structure of the dinuclear cyclopalladated compounds of methyl (E)-4-(benzylideneamino)benzoate with acetato and chlorido bridge ligands: Study of their splitting reactions with pyridine. Journal of Organometallic Chemistry, 815-816, pp. 44 - 52 . Institutional Repository . ISSN: 0022-328X
Sabaté, F.; Gavara, R.; Giannicchi, I.; Bosque, R.; Dalla Cort, A.; Rodríguez, L. (2016). Ternary assemblies comprising metal-salophen complexes and 4,4-bipyridine. New Journal of Chemistry, 40, pp. 5714 - 5721 . Institutional Repository . ISSN: 1144-0546
Gómez, J.; Leiva ,N. ; Arancibia, R.;Oyarzo, J.; Buono-Cuore, G.E.; Klahn, A.H.; Artigas, V.; Fuentealba, M.; Bosque, R.; Aullón, G.; López, C.;Font-Bardía, M.; Clavet, T. (2016). Synthesis, characterization, crystal structures and computational studies on novel cyrhetrenyl hydrazones. Journal of Organometallic Chemistry, 819, pp. 129 - 137 . Institutional Repository . ISSN: 0022-328X
López, C.; Bosque, R.; Pujol, M.; Simó, J.; Sevilla, E.; Font-bardía, M.; Messeguer, R.; Calvis, C. (2014). Experimental and Theoretical Studies of the Factors Affecting the Cycloplatination of the Chiral Ferrocenylaldimine (SC)-[(η5-C5H5)Fe{(η5-C5H4) C(H)=N CH(Me)(C6H5)}]. Inorganics, 2, pp. 620 - 648 . Institutional Repository . ISSN: 2304-6740
González, A.; Granell, J.; López, C.; Bosque, R.; Rodríguez, L.; Font-Bardia, M.; Calvet, T.; Solans, X. (2013). Hemilabile and luminescent palladium(II) azo-2-phenylindole complexes. Journal of Organometallic Chemistry, 726, pp. 21 - 31 . https://doi.org/10.1016/j.jorganchem.2012.11.036 . ISSN: 0022-328X
Caubet, A.; Bosque, R.; Molins, E.; Barros, F.J; Luna, F. (2012). Study of the different behaviour of thiazolin and thiazin indazole derivatives with palladium(II) acetate. Journal of Organometallic Chemistry, 701, pp. 36 - 42 . ISSN: 0022-328X
López, C.; González, A.; Bosque, R.; Basu, P. K.; Font-Bardía, M.; Calvet, T. (2012). Platinum(II) and palladium(II) complexes derived from 1-ferrocenylmethyl-3,5-diphenylpyrazole. Coordination, cyclometallation or transannulation?. RSC Advances, 2(5), pp. 1986 - 2002 . https://doi.org/10.1039/c1ra01080h . ISSN: 2046-2069
Talancón, D.; Bosque, R.; López, C. (2010). Study of the effect induced by the substituents on the ring-chain tautomerism of schiff bases derived from norephedrine. Journal of Organic Chemistry, 75(10), pp. 3294 - 3300 . https://doi.org/10.1021/jo100255k . ISSN: 0022-3263
Albert, J.; Bosque, R.; Crespo, M.; Granell, J.; Rodríguez, J.; Zafrilla, J. (2010). Platinum-mediated C-H bond activation of arene solvents and subsequent C-C bond formation. Organometallics, 29(20), pp. 4619 - 4627 . https://doi.org/10.1021/om100743z . ISSN: 0276-7333
Bosque, R.; Caubet, A.; Granell, J.; Mestres, L.; Seco, M. (2010). 'El racó del color': una aproximació a la interacció de la radiació electromagnètica amb la matèria. Educació Química. EduQ, 2010(5), pp. 26 - 31 . https://doi.org/10.2436/20.2003.02.37 . ISSN: 2013-1755
Jover, J.; Bosque, R.; Sales, J. (2009). Quantitative structure-property relationship estimation of cation binding affinity of the common amino acids. Journal of Physical Chemistry A, 113(15), pp. 3703 - 3708 . https://doi.org/10.1021/jp810391z . ISSN: 1089-5639
Jover, J.; Bosque, R.; Martinho Simoes, J.A.; Sales, J. (2008). Estimation of enthalpies of formation of organometallic compounds from their molecular structures. Journal of Organometallic Chemistry, 693, pp. 1261 - 1268 . https://doi.org/10.1016/j.jorganchem.2008.01.021 . ISSN: 0022-328X
Jover, J.; Bosque, R.; Sales, J. (2008). QSPR Prediction of pKa for Benzoic Acids in Different Solvents. Qsar & Combinatorial Science, 27(5), pp. 563 - 581 . https://doi.org/10.1002/qsar.200710095 . ISSN: 1611-020X
López, C.; Gonzalez, A.; Moya, C.; Bosque, R.; Solans, X.; Font-Bardía, M. (2008). Cyclopalladation of 3-methoxyimino-2-phenyl-3H-indoles. Journal of Organometallic Chemistry, 693(17), pp. 2877 - 2886 . https://doi.org/10.1016/j.jorganchem.2008.05.043 . ISSN: 0022-328X
Pérez, S.; López, C.; Bosque, R.; Solans, X.; Font-Bardía, M.; Roig, A.; Molins, E.; van Leeuwen, P. W. N. M.; van Strijdonck, G. P. F. and Freixa, Z. (2008). Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)-Allyl Complexes [Pd(η3-1-R1-C3H4){FcCHdN-CH2-(CH2)n-NMe2}][PF6] {Fc ) (η5-C5H5)Fe(η5-C5H4), n ) 2 or 1, and R1 ) H or Ph}. Organometallics, 27(17), pp. 4288 - 4299 . https://doi.org/10.1021/om7012452 . ISSN: 0276-7333
Jover, J.; Bosque, R.; Sales, J. (2008). QSPR Prediction of pK for Aliphatic Carboxylic Acids and Anilines in Different Solvents. Qsar & Combinatorial Science, 27(10), pp. 1204 - 1215 . https://doi.org/10.1002/qsar.200810049 . ISSN: 1611-020X
Jover, J.; Bosque, R.; Sales, J. (2008). A comparison of the binding affinity pf the common amino acids with different metal cations. Dalton Transactions, pp. 6441 - 6453 . https://doi.org/10.1039/b805860a . ISSN: 1477-9226
Jover, J.; Bosque, R.; Sales, J. (2007). Neural Network Based QSPR Study for Predicting pKa of Phenols in Different Solvents. Qsar & Combinatorial Science, 26(3), pp. 385 - 397 . https://doi.org/10.1002/qsar.200610088 . ISSN: 1611-020X
López, C.; Bosque, R.; Pérez, S.; Roig, A.; Molins, E.; Solans, X.; Font-Fardía, M. (2006). Relationships between 57Fe Mossbauer parameters, electrochemical properties and the structures of ferrocenylketimines. Journal of Organometallic Chemistry, 691, pp. 475 - 484 . https://doi.org/10.1016/j.jorganchem.2005.09.020 . ISSN: 0022-328X
Bosque, R.; Crespo, M.; Evangelio, E.; Font-Bardia, M.; Solans, X. (2005). Oxidative addition to dimethylplatinum(II) compounds containing bulky nitrogen ligands: crystal structures of compounds [PtMe3I{(Me2NCH2CH2CH)Ar}] (Ar = phenantryl or anthryl). Journal of Organometallic Chemistry, 690, pp. 2062 - 2070 . https://doi.org/10.1016/j.jorganchem.2004.12.017 . ISSN: 0022-328X
Bosque, R.; Maseras, F. (2005). A theoretical assessment of the thermodynamic preferences in the cyclopalladation of amines. European Journal of Inorganic Chemistry(20), pp. 4040 - 4047 . https://doi.org/10.1002/ejic.200500158 . ISSN: 1434-1948
Pérez, S.; López, C.; Caubet, A.; Bosque, R.; Solans, X.; Font-Bardía, M.; Roig, A.; Molins, E. (2004). Novel Five-Membered pallada- and Platinacycles containing a [C(sp2 , ferrocene, N,S]- Terdentate Ligand. Theoretical Interpretation of Their Electrochemical and Electronic Properties Based on Density Functional Calculations. Organometallics, 23, pp. 224 - 236 . https://doi.org/10.1021/om030520d . ISSN: 0276-7333
Jover, J.; Bosque, R.; Sales, J. (2004). Determination of Abraham Solute Parameters from Molecular Structure. Journal of Chemical Information and Computer Sciences, 44(3), pp. 1098 - 1106 . https://doi.org/10.1021/ci049943w . ISSN: 0095-2338
Jover, J.; Bosque, R.; Sales, J. (2004). Determination of Lithium Cation Basicity from Molecular Structure. Journal of Chemical Information and Computer Sciences, 44(5), pp. 1727 - 1736 . https://doi.org/10.1021/ci0498362 . ISSN: 0095-2338
Bosque, R.; Sales, J. (2003). A QSPR study of O-H bond dissociation energy in phenols. Journal of Chemical Information and Computer Sciences, 43(2), pp. 637 - 642 . https://doi.org/10.1021/ci025632e . ISSN: 0095-2338
López, C.; Bosque, R.; Arias, J.; Evangelio, E.; Solans, X.; Font-Bardia, M. (2003). Activation of σ(C-H) bonds of [Fe{(η5-C5H4-C(Me)=N-N=C(H)(C6H3-2,6-R)}2] (with R = Cl or H) promoted by palladium (II). Journal of Organometallic Chemistry, 672, pp. 34 - 42 . https://doi.org/10.1016/S0022-328X(03)00137-2 . ISSN: 0022-328X
Bosque, R; Sales, J.; Bosch, E.; Rosés, M.; García Álvarez-Coque, M.C.; Torres-Lapasió, J.R. (2003). A QSPR study of the p solute polarity parameter to estimate retention in HPLC. Journal of Chemical Information and Computer Sciences, 43, pp. 1240 - 1247 . https://doi.org/10.1021/ci0340660 . ISSN: 0095-2338
López, C.; Caubet, A.; Bosque, R.; Solans, X.; Font-Bardia, M. (2002). Palladium(II) Induced Preferential Activation of the σ(Csp3-H) versus the σ(Csp2, ferrocene-H Bond of (Sc)-[(η5-C5H5)Fe{(η5-C5H4)-CH=N-CH(CO2Me)CH2-CH2-SMe}]. Journal of Organometallic Chemistry, 645(1-2), pp. 146 - 151 . https://doi.org/10.1016/S0022-328X(01)01353-5 . ISSN: 0022-328X
Bosque, R.; Sales, J. (2002). Polarizabilities of solvents from the chemical composition. Journal of Chemical Information and Computer Sciences, 42(5), pp. 1154 - 1163 . https://doi.org/10.1021/ci025528x . ISSN: 0095-2338
López, C.; Caubet, A.; Pérez, S.; Bosque, R.; Solans, X.; Font-Bardia, M. (2002). Synthesis, X-ray crystal structure and solution behaviour of [Zn(η5-C5H5)Fe[(η5C5H4)-CH=N-(CH2)sub>3-NMe2]}Cl2]. Polyhedron, 21(23), pp. 2361 - 2367 . https://doi.org/10.1016/S0277-5387(02)01181-6 . ISSN: 0277-5387
Bosque, R.; Sales, J. (2001). A QSPR Study of 31-P NMR Chemical Shifts of Phosphines. Journal of Chemical Information and Computer Sciences, 41(1), pp. 225 - 232 . https://doi.org/10.1021/ci000458k . ISSN: 0095-2338
Pérez, S.; Bosque, R.; López, C.; Solans, X.; Font-Bardía, M. (2001). Trans- influences in mononuclear cyclopalladated compounds containing a σ(Pd-Csp2, ferrocene) Bond. X-Ray Crystal structures of [Pd{(η5 -C5H3)CH=N-CH2-C6H5 }Fe(η5-C5H5}(X)(PPh3] with X- = Br- or I-. Journal of Organometallic Chemistry, 625(1), pp. 67 - 76 . https://doi.org/10.1016/S0022-328X(00)00900-1 . ISSN: 0022-328X
Bosque, R.; Benito, M.; López, C. (2001). Influence of the substituents on the electrochemical properties in nine-membered palladacycles of general formula [Pd{[R1-C=C-R2)2-(η-5- C5H3)-C(R3)=N-R4]Fe(η- 5-C5H5)}Cl]. New Journal of Chemistry, 25, pp. 827 - 833 . https://doi.org/10.1039/b101338f . ISSN: 1144-0546
López, C.; Bosque, R.; Solans, X.; Font-Bardía, M. (2001). Factors affecting the lability of the Pd-N bonds in palladacycles containing a σ(Pd-Csp2, ferrocene) Bond. X-ray crystal structures of [Pd{(η5-C5H3)CMe=N-R}Fe(η5 -C5H5}(Cl)(L)] {with R = CH2 and L = PEt 3 or R = C6H4-4-Me and L = PPh2 Et}. Polyhedron, 20, pp. 987 - 994 . https://doi.org/10.1016/S0277-5387(01)00739-2 . ISSN: 0277-5387
Albert, J.; Bosque, R.; Cadena, J. M.; Delgado, S.; Granell, J. (2001). Optically active cyclopalladated compounds containing P-chiral ligands. Restricted rotation around the Pd-P bond. Journal of Organometallic Chemistry, 634, pp. 83 - 89 . https://doi.org/10.1016/S0022-328X(01)01111-1 . ISSN: 0022-328X
Albert, J.; Bosque, R.; Granell, J.; Tavera, R. (2001). A high-yield method of synthesis of the acetato bridged endo-cyclopalladated dimer of benzyl-benzylidene-amine. Polyhedron, 20(22), pp. 3225 - 3229 . https://doi.org/10.1016/S0277-5387(01)00931-7 . ISSN: 0277-5387
Albert, J.; Bosque, R.; Granell, J.; Tavera, R. (2000). Cyclometallation of anthracen-9-ylmethylene-phenyl-amine by palladium (II) compounds. Journal of Organometallic Chemistry, 595(1), pp. 54 - 58 . https://doi.org/10.1016/S0022-328X(99)00567-7 . ISSN: 0022-328X
Albert, J.; Bosque, R.; Cadena, J.M.; Granell, J.R.; Muller, G.; Ordinas, J.I. (2000). Synthesis and resolution of benzylisopropylphenylphosphine, a monodentate P-chiral ligand. Tetrahedron-Asymmetry, 11, pp. 3335 - 3343 . https://doi.org/10.1016/S0957-4166(00)00300-1 . ISSN: 0957-4166
Bosque, R.; López, C.; Solans, X.; Font-Bardía, M. (1999). Heterodi- and heterotrimetallic compounds containing five-membered rings and σ(Pd-C-sp2, ferrocene) bonds. X-ray crystal structure of the meso-form of [Pd 2{Fe[(η5-C5H3)-C(CH3)= N-C6H5]}2Cl2(PPh3)2]. Organometallics, 18(7), pp. 1267 - 1274 . https://doi.org/10.1021/om980834e . ISSN: 0276-7333
Caubet, A.; López, C.; Bosque, R.; Solans, X.; Font-Bardia, M. (1999). Palladium (II) and Platinum (II) Compounds Containing Bi- and Terdentate Ferrocenyl Ligands. X-Ray Crystal Structure of cis-[Pd{(η5 -C5H5)Fe(η5-C5H4)-CH=N-CH2- CH2-N(CH3)2]}Cl2. Journal of Organometallic Chemistry, 577, pp. 292 - 304 . https://doi.org/10.1016/S0022-328X(98)01077-8 . ISSN: 0022-328X
Renkema, K.B.; Bosque, R.; Streib, W.E.; Maseras, F.; Eisenstein, O.; Caulton, K.G. (1999). Phosphine dissociation mediates C-H cleavage of fluoroarenes by OsH(C6H5)(CO)(PtBu2Me) 2. Journal of the American Chemical Society, 121(47), pp. 10895 - 10907 . https://doi.org/10.1021/ja990523a . ISSN: 0002-7863
López, C.; Bosque, R.; Solans, X.; Font-Bardia, M. (1998). Influence of the electronic effects of phosphine ligands upon the properties of cyclopalladated complexes containing a σ(Pd-Csp2,ferrocene)bond. X-ray crystal structures of: [Pd{(η5-C5H5)Fe[(η5-C5H3)-C(Me)=N(C6H4-4-Me)]}Cl(PPh3)] and [Pd{(η5-C5H5)Fe[(η5-C5H 3)-CH2-NMe2]}Cl(PPh3)]. New Journal of Chemistry, 22, pp. 977 - 982 . https://doi.org/10.1039/a801737i . ISSN: 1144-0546
Bosque, R.; López, C. (1998). Palladium (II) compounds containing mono- and bidentate primary ferrocenylamines. A study of cyclopalladation of: [(η5-C5 H5)Fe{(η5-C5H4)-(CH2)n -NH2}] {with n=1or 2}. Polyhedron, 18, pp. 135 - 143 . https://doi.org/10.1016/S0277-5387(98)00276-9 . ISSN: 0277-5387
Bosque, R.; Fantacci, S.; Maseras, F.; Clot, E.; Eisenstein,O.; Perutz, R.N.; Renkema, K.B.; Caulton, K.G. (1998). Inertness of the Arly-F Bond toward oxidative addition to osmium and rhodium complexes: thermodynamic or kinetic origin?. Journal of the American Chemical Society, 120, pp. 12634 - 12640 . https://doi.org/10.1021/ja9824573 . ISSN: 0002-7863
López, C.; Bosque, R.; Sainz, D.; Solans, M.; Font-Bardía, M. (1997). A new reagent for chiral recognition contianing a Five-membered Palladacycle with σ(Pd-Csp2, ferrocene)Bond. Organometallics, 16, pp. 3261 - 3266 . https://doi.org/10.1021/om970098z . ISSN: 0276-7333
Bosque, R.; Maseras, F.; Eisenstein, O.; Patel, B.P.; Yao, W.; Crabtree, R.H. (1997). Site Preference Energetics, Fluxionality and Intramolecular M-H...H-N Hydrogen Bonding in Dodecahedral Transition Metal Polyhydride. Inorganic Chemistry, 36, pp. 5505 - 5511 . https://doi.org/10.1021/ic970084l . ISSN: 0020-1669
López, C.; Bosque, R.; Solans, X.; Font-Bardía, M. (1997). Palladium(II) compounds containing σ[Pd-Csp2(ferrocene)] bonds and ferrocenyloximes as bidentate {CN}-ligands. X ray-crystal structure of [Pd{[(η5-C5H3) C(CH3)=N(OH)]Fe(η5-C5H5)}Cl(PPh3)]. Journal of Organometallic Chemistry, 539, pp. 99 - 107 . https://doi.org/10.1016/s0022-328x(97)00030-2 . ISSN: 0022-328X
López, C.; Bosque, R.; Solans, X.; Font-Bardía, M. (1997). Stereochemical rigidity in a trimetallic complex. X-ray crystal structure of trans-[Pd{(η5-C5H5)Fe[(η5- C5H4-CH=N-N-(CH3)2})Cl2]. Journal of Organometallic Chemistry, 535, pp. 99 - 105 . https://doi.org/10.1016/S0022-328X(96)06945-8 . ISSN: 0022-328X
Bosque, R.; Caubet, A.; López, C.; Espinosa, E.; Molins, E. (1997). Synthesis, Characterization and Study of the Properties of Heterobimetallic Compounds Containing Ferrocenyl Units. X-ray Crystal Structure of [{Zn(η5-C5H5)Fe[(η5-C5H4-CH =N-CH2-CH2-N(CH3)2]Cl2]. Journal of Organometallic Chemistry, 544, pp. 233 - 241 . https://doi.org/10.1016/S0022-328X(97)00298-2 . ISSN: 0022-328X
López, C.; Bosque, R.; Solans, X.; Font-Bardia, M. (1997). Activation of σ(C-H) bonds in ferrocenylhydrazones derived from acetylferrocene. Journal of Organometallic Chemistry, 547, pp. 309 - 317 . https://doi.org/10.1016/S0022-328X(97)00388-4 . ISSN: 0022-328X
López, C.; Bosque, R. (1996). Mono-and Bis(cyclopalladation) of the Bis (Ferrocenyl) imine [(η5-C5H5)Fe{(η5H4-CH=N-C6H 4-(2-CH3)}]2. Journal of Organometallic Chemistry, 524, pp. 247 - 252 . https://doi.org/10.1016/S0022-328X(96)06404-2 . ISSN: 0022-328X
Bosque, R.; López, C.; Sales, J. (1996). Substituent Effects in the Electrochemical Behaviour of Iron (II) in Ferrocenylimines and Their Cyclopalladated Compounds. Inorganica Chimica Acta, 244(1), pp. 141 - 145 . https://doi.org/10.1016/0020-1693(95)04744-1 . ISSN: 0020-1693
Bosque, R.; López, C.; Sales, J.; Solans, X.; Silver, J. (1996). A bis (cyclopalladated) tetranuclear derivative of methyl ferrocenyl ketoneazine,[{Pd[(η5-C5H5)Fe[(η5-C5H3 )=N]Cl(PPh3)}2]. Journal of the Chemical Society, Dalton Transactions(15), pp. 3195 - 3200 . https://doi.org/10.1039/dt9960003195 . ISSN: 1472-7773
López, C.; Bosque, R.; Solans, X.; Font-Bardia, M. (1996). Synthesis and characterization of optically active cyclopalladated compounds containing ferrocenyl units. Tetrahedron-Asymmetry, 7(9), pp. 2527 - 2530 . https://doi.org/10.1016/0957-4166(96)00325-4 . ISSN: 0957-4166
López, C.; Bosque, R.; Solans, X.; Font-Bardia, M. (1996). Steric effects in ferrocenylketimines and Aldimines. X-Ray Crystal Structure of [Fe(η5-C5H5){(η5-C5 H4)C(C6H5)R'}](with R'=C6H4-4-CH3or C6H4-2-CH3). New Journal of Chemistry, 20, pp. 1285 - 1292 . ISSN: 1144-0546
Hartwig, J.F.; He, X.; Muhoro, C.N.; Eisenstein, O.; Bosque, R.; Maseras, F. (1996). Catecholborane Bound to Titanocene. Unusual Coordination of Ligand σ- Bonds. Journal of the American Chemical Society, 118(44), pp. 10936 - 10937 . https://doi.org/10.1021/ja962086v . ISSN: 0002-7863
López, C.; Bosque, R.; Solans, X.; Font-Bardía, M.; Silver, J., Fern, G. (1995). Alkyne insertions into the σ-Pd-C(sp2, ferrocene) bond of cyclopalladated complexes containing Schiff bases derived from the ferrocene. X-Ray crystal Structure of [Pd{[(EtC=CEt) 2 (η5-C5H3)-C(R)=N-C6H5)Fe(η5 -C5H5)}Cl], with R=CH3 or H. Journal of the Chemical Society, Dalton Transactions(11), pp. 1839 - 1849 . https://doi.org/10.1039/dt9950001839 . ISSN: 1472-7773
Bosque, R.; López, C.; Sales, J.; Tramuns, D.; Solans, X. (1995). Activation of σ(C-H) bonds in Ferrocenyl- and bis(ferrocenyl)-imines promoted by Palladium. Journal of the Chemical Society, Dalton Transactions, pp. 2445 - 2452 . https://doi.org/10.1039/dt9950002445 . ISSN: 1472-7773
Bosque, R.; López, C.; Sales, J. (1995). Schiff Bases Derived from Aminomethylferrocene and their Cyclopalladated Derivatives. Journal of Organometallic Chemistry, 498, pp. 147 - 154 . https://doi.org/10.1016/0022-328X(95)05511-M . ISSN: 0022-328X
López, C.; Bosque, R.; Solans, X.; Font-Bardia, M.; Silver, J.; Fern, G. (1995). Palladium(II)-induced preferential activation of the σ[Csp2(phenyl)-Cl] bond versusσ[Csp2(ferrocene)-H]. Crystal structure of [Fe(η5-C5H5){η5-C5H4CH2N CH(C6H3Cl2-2,6)}]. Journal of the Chemical Society, Dalton Transactions(24), pp. 4053 - 4058 . https://doi.org/10.1039/dt9950004053 . ISSN: 1472-7773
Bosque, R.; López, C.; Sales, J.; Solans, X.; Font-Bardía, M (1994). Influences of the Substituents at the Iminic Carbon Atoms (Hydrogen versus Methyl) upon the properties of ferrocenylimines and their Cyclopalladated Derivatives. Journal of the Chemical Society, Dalton Transactions(5), pp. 735 - 745 . https://doi.org/10.1039/dt9940000735 . ISSN: 1472-7773
Bosque, R.; Font-Bardía, M.; López, C.; Sales, J.; Silver, J.; Solans, X (1994). Electronic Conjugation Pathways in Ferrocenyl Schiff Bases. Journal of the Chemical Society, Dalton Transactions(5), pp. 747 - 752 . https://doi.org/10.1039/dt9940000747 . ISSN: 1472-7773
López, C.; Bosque, R.; Solans, X.; Font-Bardía, M.; Tramuns, D.; Fern, G.; Silver, J (1994). Effects of the nature of the nitrogen donor atom (sp2 versus sp3) upon the properties and chemistry of palladated complexes with σ (Pd-Csp2, ferrocene) bonds. Journal of the Chemical Society, Dalton Transactions(20), pp. 3039 - 3046 . https://doi.org/10.1039/dt9940003039 . ISSN: 1472-7773
Bosque, R.; López, C.; Sales, J.; Solans, X. (1994). Schiff bases derived from Benzoylferrocene and their Cyclopalladated derivatives.X-Ray Crystal Structure of [Pd{(η5-C5H5)Fe((η5-C5H3)C(C6H5)=N-C6 H5]}CI(PPh3)]. Journal of Organometallic Chemistry, 483(1-2), pp. 61 - 71 . https://doi.org/10.1016/0022-328X(94)87148-5 . ISSN: 0022-328X
Bosque, R.; Granell, J.; Sales, J.; Solans, X.; Font Bardía, M (1993). Reactivity of Cyclometallated compounds of N-benzylideneamines. Synthesis and X-Ray structure of [Pd-{1-CH2-2(CH=NC6H5)-3,5(CH3)2 C6H2}(2,4-lut)]ClO4. Journal of Organometallic Chemistry, 453, pp. 147 - 154 . https://doi.org/10.1016/0022-328X(93)80340-H . ISSN: 0022-328X
Lázaro, A.; Cunha, C.; Bosque, R.; Pina, J.; Ward, J.S.; Truong, K.N.; Rissanen, K.; Lima, J.C.; Crespo, M.; Seixas de Melo, J.S.; Rodríguez, L. (2020). Room-Temperature Phosphorescence and Efficient Singlet Oxygen Production by Cyclometalated Pt(II) Complexes with Aromatic Alkynyl Ligands. Inorganic Chemistry, 59(12), pp. 8220 - 8230 . Institutional Repository . ISSN: 0020-1669
Huentupil,Y. ;Chung,P.; Novoa, N. ; Arancibia, R.; Roussel, P.; Oyarzo ,J. ; Klahn, A.H. ;C. Silva, C. ; Calvis, C.; Messegue,R.; Bosque, R. ; López, C. (2020). Novel multifunctional and multitarget homo- (Fe-2) and heterobimetallic [(Fe,M) with M = Re or Mn] sulfonyl hydrazones. Dalton Transactions, 49 , pp. 12249 - 12265 . https://doi.org/10.1039/d0dt01756f . ISSN: 1477-9226
Albert, J.; Bosque, R.; Crespo, M.; Granell, J.; López, C.; Cortés, R.; Gonzalez, A.; Quirante, J.; Calvis, C.; Messeguer, R.; Baldomà, L.; Badia, J.; Cascante, M. (2013). Pt(II) complexes with (N,N') or (C,N,E)- (E = N,S) ligands: Cytotoxic studies, effect on DNA tertiary structure and structure-activity relationships. Bioorganic & Medicinal Chemistry, 21, pp. 4210 - 4217 . https://doi.org/10.1016/j.bmc.2013.05.005 . ISSN: 0968-0896
Albert, J.; Bosque, R.; D'Andrea, L.; Granell, J.; Calvet, T.; Font-Bardia, M.; Calvet T. (2011). Synthesis of cyclopalladated derivatives of (E)-N-benzylidene-2-(2,6-dichlorophenyl)ethanamine and their reactivity toward monodentate and symmetric bidentate Lewis bases. European Journal of Inorganic Chemistry(24), pp. 3617 - 3631 . https://doi.org/10.1002/ejic.201100293 . ISSN: 1434-1948
Lázaro, Ariadna; Bosque, Ramon; Ward, Jay S.; Rissanen, Kari; Crespo, Margarita; Rodríguez, Laura (2023). Towards NIR emission in Pt(II)-cyclometallated compounds. From excimers formation to AIE. Inorganic Chemistry . https://doi.org/10.1021/acs.inorgchem.2c03490 . ISSN: 0020-1669
Lázaro, Ariadna; Bosque, Ramon; Ward, Jas S.; Rissanen, K.; Crespo,M. ,Rodríguez,L. (2023). Toward Near-Infrared Emission in Pt(II)-Cyclometallated Compounds: From Excimers' Formation to Aggregation-Induced Emission. Inorganic Chemistry . https://doi.org/10.1021/acs.inorgchem.2c03490 . ISSN: 0020-1669

Activity interests

Synthesis and characterization of organometallic and coordination compounds . Departament de Química Inorgànica de la Universitat de Barcelona
  • Ciclometalación
  • Paladio
  • Iminas
Mössbauer Spectroscopy of ferrocene derivatives . Departament of Chemistry and Biological Chemistry (University of Essex) . (07/1992 - 09/1996)
  • Paladio
  • Iminas
  • Espectroscopía Mössbauer
  • Ferroceno
ab initio calculation of organometallic compounds . Laboratoire de Structure et Dynamique des Systèmes moléculaires et Solides (Université de Montpellier II) . (01/1996 - 12/1996)
  • Cálculos
  • Química teórica
  • DFT
Molecular modelling of inorganic and organometalic systems . Universitat de Barcelona . (01/01/1997)
  • DFT calculations
  • Compostos organometàl.lics
Quantitative structure-propieties relationships (QSPR) . Universitat de Barcelona
  • QSPR
  • QSAR

Other Tasks

Coordinador de la asignatura Química Inorgánica de la Titulación de Farmacia () . 01/10/2003
Coordinador de l'assignatura Química General i Inorgànica de la llicenciatura / grau de Farmàcia () . 01/09/2011
Vice Dean of Safety, Health and Sustainability of the Faculty of Chemistry () . 13/01/2021